PTHH:

\(CaCO_3+2HCl\rightarrow CaCl_2+H_2O+CO_2\uparrow\)

0,15                                                     0,15 

\(CaO+2HCl\rightarrow CaCl_2+H_2O\)

Ta có: \(n_{CO_2}=\dfrac{3,36}{22,4}=0,15\left(mol\right)\)

\(\Rightarrow m_{CaCO_3}=0,15\cdot100=15\left(g\right)\)

\(\Rightarrow m_{CaO}=20,6-15=5,6\left(g\right)\)

\(\Rightarrow\%m_{CaCO_3}=\dfrac{15\cdot100}{20,6}\approx73\%\)

\(\Rightarrow\%m_{CaO}=100\%-73\%=27\%\)

MgO+H₂SO₄\(\rightarrow\)MgSO₄+H₂O(1)

MgCO₃+H₂SO₄\(\rightarrow\)MgSO₄+ CO₂+H₂O(2)

- Theo PTHH (2): \(n_{MgCO_3}=n_{CO_2}=\dfrac{V}{22,4}=\dfrac{2,24}{22,4}=0,1mol\)

\(m_{MgCO_3}=n.M=0,1.84=8,4g\)

m_MgO=16,4-8,4=8g\(\rightarrow\)\(n_{MgO}=\dfrac{m}{M}=\dfrac{8}{40}=0,2mol\)

\(\%MgCO_3=\dfrac{8,4.100}{16,4}\approx51,22\%\)

%MgO=100%-51,22%=48,78%

- Theo PTHH (1,2) ta có:\(n_{MgSO_4}=n_{MgO}+n_{MgCO_3}=0,1+0,2=0,3mol\)

\(n_{Ba\left(OH\right)_2}=0,3.1,5=0,45mol\)

- Gọi x là số mol H₂SO₄ còn dư sau phản ứng (1,2).

H₂SO₄+Ba(OH)₂\(\rightarrow\)BaSO₄\(\downarrow\)+2H₂O(3)

MgSO₄+Ba(OH)₂\(\rightarrow\)BaSO₄\(\downarrow\)+Mg(OH)₂\(\downarrow\)(4)

- Kết tủa tạo thành gồm BaSO₄(pu 3,4) và Mg(OH)₂(pu 4). Như vậy dd B thu được có khả năng còn dư Ba(OH)₂ là chất tan duy nhất.

Ta có: 233x+233.0,3+58.0,3=110,6\(\rightarrow\)x=0,1mol

- Theo PTHH(3,4): \(n_{Ba\left(OH\right)_2}=n_{H_2SO_4}+n_{MgSO_4}=0,1+0,3=0,4mol\)

\(n_{Ba\left(OH\right)_2\left(dư\right)}=0,45-0,4=0,05mol\)

\(C_{M_{Ba\left(OH\right)_2}}=\dfrac{n}{V}=\dfrac{0,05}{0,5}=0,1M\)

trần hữu tuyển Hồ Hữu Phước Nguyễn Thị Kiều

\(n_{H2}=\dfrac{4,48}{22,4}=0,2\left(mol\right)\)
Pt : \(Fe+2HCl\rightarrow FeCl_2+H_2|\)

        1          2            1           1

       0,2       0,4         0,2         0,2

      \(Fe_2O_3+6HCl\rightarrow2FeCl_3+3H_2O|\)

          1            6               2              3

         0,2         1,2            0,4

\(n_{Fe}=\dfrac{0,2.1}{1}=0,2\left(mol\right)\)

⇒ \(m_{Fe}=0,2.56=11,2\left(g\right)\)

\(m_{Fe2O3}=27,2-11,2=16\left(g\right)\)

⁰/₀Fe = \(\dfrac{11,2.100}{27,2}=41,18\)⁰/₀

⁰/₀Fe₂O₃ = \(\dfrac{16.100}{27,2}=58,82\)⁰/₀

b) Có : \(m_{Fe2O3}=16\left(g\right)\)

 \(n_{Fe2O3}=\dfrac{16}{160}=0,1\left(mol\right)\)

\(n_{HCl\left(tổng\right)}=0,4+1,2=1,6\left(mol\right)\)

\(V_{HCl}=\dfrac{1,6}{2}=0,8\left(l\right)\)

c) \(n_{FeCl2}=\dfrac{0,2.1}{1}=0,2\left(mol\right)\)

   \(n_{FeCl3}=\dfrac{1,2.2}{6}=0,4\left(mol\right)\)

  \(C_{M_{FeCl2}}=\dfrac{0,2}{0,8}=0,25\left(M\right)\)

  \(C_{M_{FeCl3}}=\dfrac{0,4}{0,8}=0,5\left(M\right)\)

 Chúc bạn học tốt

 \(n_{CO2}=\dfrac{2,24}{22,4}=0,1\left(mol\right)\)

PTHH : \(CaO+2HCl\rightarrow CaCl_2+H_2O\) (1)

\(CaCO_3+2HCl\rightarrow CaCl_2+H_2O+CO_2\) (2)

a) Theo Pt : \(n_{CO2}=n_{CaCO3}=0,1\left(mol\right)\)

\(m_{CaCO3}=0,1100=10\left(g\right)\)

\(m_{CaO}=12,8-10=2,8\left(g\right)\)

b) Chắc tính V của dd HCl đã dùng 

(1) \(n_{CaO}=\dfrac{2,8}{56}=0,05\left(mol\right)\) , \(n_{HCl}=2n_{CaO}=0,1\left(mol\right)\)

(2) \(n_{HCl}=2n_{CaCO3}=0,2\left(mol\right)\)

\(\Rightarrow V_{ddHCl}=\dfrac{0,1+0,2}{1}=0,3\left(l\right)=300\left(ml\right)\)

\(n_{H_2}=\dfrac{6,72}{22,4}=0,3\left(mol\right)\\ n_{SO_2}=\dfrac{2,24}{22,4}=0,1\left(mol\right)\)

PTHH:

2Al + 3H₂SO₄ ---> Al₂(SO₄)₃ + 3H₂

0,2<-----0,3<-----------0,1-------------0,3

Cu + 2H₂SO₄ ---> CuSO₄ + SO₂ + 2H₂O

0,1<---------------------------------0,1

\(\rightarrow\left\{{}\begin{matrix}m_{Al}=0,2.27=5,4\left(g\right)\\m_{Cu}=0,1.64=6,4\left(g\right)\end{matrix}\right.\\ \rightarrow\left\{{}\begin{matrix}\%m_{Al}=\dfrac{5,4}{11,8}.100\%=45,76\%\\\%m_{Cu}=100\%-45,76\%=54,24\%\end{matrix}\right.\)

\(m_{ddA}=\dfrac{0,3.98}{20\%}+5,4-0,3.2=151,8\left(g\right)\\ C\%_{Al_2\left(SO_4\right)_3}=\dfrac{0,1.342}{151,8}.100\%=22,53\%\)

tk:

Fe + 2HCl -> FeCl2 + H2

          0.2                     0.1

FeO + 2HCl -> FeCl2 + H2O

 0.1       0.2

a.\(nH2=\dfrac{2.24}{22.4}=0.1mol\)

\(\%mFe=\dfrac{0.1\times56\times100}{12.8}=43.8\%\)

\(\%mFeO=100-43.8=56.2\%\)

b.\(nFeO=\dfrac{12.8-\left(0.1\times56\right)}{56+16}=0.1mol\)

\(V_{HCl}=\dfrac{0.2+0.2}{2}=0.2l\)